Statistical Mechanics
Bridging Microscopic and Macroscopic
Microstates and the Boltzmann Definition of Entropy
For a system with accessible microstates, Boltzmann's entropy: In the canonical ensemble (fixed , , ), the probability of microstate with energy :<br> is the partition function.
Thermodynamic Quantities from Z
All thermodynamic quantities follow from :
- Free energy:
- Average energy: where
- Entropy:
- Heat capacity:
Quantum Statistics
Bosons obey Bose-Einstein statistics (photons, phonons) and can occupy the same state. Fermions obey Fermi-Dirac statistics (electrons) — no two in the same quantum state (Pauli exclusion). Classical limit: Maxwell-Boltzmann.
In the canonical ensemble, temperature is:
Canonical ensemble: fixed , , — system exchanges heat with reservoir.
Correct answer: Fixed (system in contact with a heat reservoir)
The partition function for a two-level system ( and ) is:
.
Correct answer:
Write the Fermi-Dirac distribution and explain what it describes.
At , all states below (Fermi energy) are filled, all above are empty.
Correct answer: . It gives the average occupation number of a quantum state with energy for fermions, where is the chemical potential.