← Back to CoursesQuantum Physics: PhD Level

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Canonical Quantization, Angular Momentum, and Spin

Manual: General · Subject: Quantum Physics

Quantize classical systems, study commutators, and analyze angular momentum and spin as foundational quantum structures.

From Poisson brackets to commutators

Canonical quantization

Canonical quantization replaces classical Poisson brackets with commutators via {f,g}PB→1iℏ[f^,g^]\{f,g\}_{\mathrm{PB}} \to \frac{1}{i\hbar}[\hat f,\hat g]. The canonical pair satisfies [x^,p^]=iℏ[\hat x,\hat p]=i\hbar.

Operator ordering and ambiguity

When classical expressions are nonlinear in xx and pp, quantization is not unique because operator ordering matters. This is one reason modern treatments often begin from symmetries, algebras, or path integrals.

Angular momentum and spin

Commutation relations

Angular momentum operators obey [J^i,J^j]=iℏ εijkJ^k[\hat J_i,\hat J_j]=i\hbar\,\varepsilon_{ijk}\hat J_k. The ladder operator method yields eigenvalues J2=j(j+1)ℏ2J^2=j(j+1)\hbar^2 and Jz=mℏJ_z=m\hbar.

Spin as an intrinsic quantum number

Spin is not literal spatial rotation of a point particle; it is an irreducible representation of the rotation group and its double cover. Spin-12\frac{1}{2} systems are described by Pauli matrices and two-component spinors.

Orbital vs intrinsic angular momentum

Orbital angular momentum

  • Arises from spatial coordinates and momenta
  • Has integer quantum numbers for single-valued wavefunctions

Spin angular momentum

  • Intrinsic representation-theoretic degree of freedom
  • Can be half-integer

What is the canonical commutation relation for position and momentum?

What are the allowed eigenvalues of J^2\hat J^2?

Spin-12\frac12 states transform under which group representation?