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Canonical Quantization and Exactly Solvable Systems

Manual: General · Subject: Quantum Physics

Quantize classical systems, analyze commutators, and solve the standard canonical models in advanced detail.

From Poisson brackets to commutators

Canonical quantization

Canonical variables obey [q^,p^]=iℏ[\hat q,\hat p]=i\hbar. Formally, this replaces Poisson brackets by {f,g}→1iℏ[f^,g^]\{f,g\}\to \dfrac{1}{i\hbar}[\hat f,\hat g], though the correspondence is subtle and constrained by ordering issues and no-go theorems.

What is the ground-state energy of the one-dimensional harmonic oscillator?

Harmonic oscillator ladder algebra

Defining a=mω2ℏ x^+i2mℏω p^a=\sqrt{\dfrac{m\omega}{2\hbar}}\,\hat x + \dfrac{i}{\sqrt{2m\hbar\omega}}\,\hat p gives H=ℏω(a†a+12)H=\hbar\omega(a^\dagger a+\tfrac12). Eigenstates ∣n⟩|n\rangle are generated algebraically and are central to quantum field theory.

Write the canonical commutation relation between position and momentum.

Particle in a box and boundary quantization

A particle confined to 0<x<L0<x<L with ψ(0)=ψ(L)=0\psi(0)=\psi(L)=0 has energies En=n2π2ℏ22mL2E_n=\dfrac{n^2\pi^2\hbar^2}{2mL^2}. This model illustrates quantization from boundary conditions rather than from algebra alone.

In the infinite square well, the allowed wave numbers are

Delta potentials and scattering intuition

The attractive delta potential V(x)=−λδ(x)V(x)=-\lambda\delta(x) supports a single bound state, while the repulsive delta acts as a singular scatterer. Such models are valuable idealizations in low-dimensional physics and cold-atom theory.

Why is operator ordering an issue in quantization?

ℹ️

Advanced note

Exactly solvable models provide benchmarks for approximations such as perturbation theory, variational methods, and numerical diagonalization.

Solving a one-dimensional bound-state problem

  1. 1

    Write the stationary Schrödinger equation Hψ=EψH\psi=E\psi.

  2. 2

    Impose boundary conditions and normalizability.

  3. 3

    Match coefficients or quantization conditions.

  4. 4

    Normalize the eigenfunctions and interpret the spectrum.

Two kinds of quantization

Canonical quantization

  • Promotes classical observables to operators
  • Uses commutator algebra
  • Sensitive to ordering ambiguities

Quantization by boundary conditions

  • Starts from wave mechanics in constrained geometry
  • Discrete spectrum arises from geometry
  • Common in wells, rings, and cavities